In a statement, the G7 group also said that Russia must stop blocking food from leaving Ukraine's ports.
Addressing the summit via video link, Ukraine's president appealed for more heavy weapons from Western allies.
G7 leaders are under pressure to be united in their approach against increasing Russian aggression.
"We will continue to provide financial, humanitarian, military and diplomatic support and stand with Ukraine for as long as it takes," they said in a strongly worded statement on Monday.